Cesium Facts

Cesium or Cs Chemical & Physical Properties

This is a sealed sample of cesium (caesium) metal. Cesium melts into a liquid just above room temperature.
This is a sealed sample of cesium (caesium) metal. Cesium melts into a liquid just above room temperature. Dnn87

Cesium or caesium is a metal with the element symbol Cs and atomic number 55. This chemical element is distinctive for several reasons. Here is a collection of cesium element facts and atomic data:

Cesium Element Facts

  • Although not a liquid at room temperature, if you hold a vial containing cesium in your hand, your body heat will melt the element into its liquid form, which resembles pale liquid gold.
  • German chemists Robert Bunsen and Gustav Kirchhoff discovered cesium in 1860 when analyzing the spectrum of mineral water. The name for the element comes from the Latin word "caesius", which means "sky blue". This refers to the color of the line in the spectrum the chemists saw that tipped them off about the new element.
  • Although the official IUPAC name for the element is cesium, several countries, including England, retain the original Latin spelling of the element: caesium. Either spelling is correct.
  • Samples of cesium are kept in sealed containers, under an inert liquid or gas or in a vacuum. Otherwise, the element would react with air or water. Cesium is the most alkaline of the elements and reacts explosively with water to produce cesium hydroxide (CsOH), a strong base that can eat through glass. Cesium spontaneously ignites in air.
  • Although francium is predicted to be more reactive than cesium, based on its location on the periodic table, so little of the element has been produced no one knows for sure. For all practical purposes, cesium is the most reactive metal known to man. According to the Allen scale of electronegativity, cesium is the most electronegative element. Francium is the most electronegative element according to the Pauling scale.
  • Cesium is a soft, ductile metal. It is readily drawn into fine wires.
  • Only one isotope of cesium occurs naturally -- cesium-133. Numerous artificial radioactive isotopes have been produced.
  • Non-radioactive cesium is not a nutritional requirement for plants or animals, but it's not particularly toxic, either. Radioactive cesium presents a health hazard because of the radioactivity, not the chemistry.
  • Cesium is used in atomic clocks, photoelectric cells, as a catalyst to hydrogenate organic compounds, and as a 'getter' in vacuum tubes. The isotope Cs-137 is used in cancer treatments, to irradiate foods, and as a tracer for drilling fluids in the petroleum industry. Nonradioactive cesium and its compounds are used for infrared flares, to make specialty glasses, and in beer brewing.
  • There are two methods used to prepare pure cesium. Calcium metal may be combined with fused cesium chloride or an electric current may be passed through a molten cesium compound.
  • Cesium is estimated to be present at an abundance of 1 to 3 parts per million in the Earth's crust, which is a fairly average abundance for a chemical element.

Cesium Atomic Data

Element Name: Cesium

Atomic Number: 55

Symbol: Cs

Atomic Weight: 132.90543

Element Classification: Alkali Metal

Discoverer: Gustov Kirchoff, Robert Bunsen

Discovery Date: 1860 (Germany)

Name Origin: Latin: coesius (sky blue); named for the blue lines of its spectrum

Density (g/cc): 1.873

Melting Point (K): 301.6

Boiling Point (K): 951.6

Appearance: extremely soft, ductile, light gray metal

Atomic Radius (pm): 267

Atomic Volume (cc/mol): 70.0

Covalent Radius (pm): 235

Ionic Radius: 167 (+1e)

Specific Heat (@20°C J/g mol): 0.241

Fusion Heat (kJ/mol): 2.09

Evaporation Heat (kJ/mol): 68.3

Pauling Negativity Number: 0.79

First Ionizing Energy (kJ/mol): 375.5

Oxidation States: 1

Electronic Configuration: [Xe] 6s1

Lattice Structure: Body-Centered Cubic

Lattice Constant (Å): 6.050

References: Los Alamos National Laboratory (2001), Crescent Chemical Company (2001), Lange's Handbook of Chemistry (1952)

 

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