Common Anions Table and Formulas List

Table Listing Common Anions

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Helmenstine, Anne Marie, Ph.D. "Common Anions Table and Formulas List." ThoughtCo, May. 5, 2017, thoughtco.com/common-anions-table-and-formulas-list-603961. Helmenstine, Anne Marie, Ph.D. (2017, May 5). Common Anions Table and Formulas List. Retrieved from https://www.thoughtco.com/common-anions-table-and-formulas-list-603961 Helmenstine, Anne Marie, Ph.D. "Common Anions Table and Formulas List." ThoughtCo. https://www.thoughtco.com/common-anions-table-and-formulas-list-603961 (accessed September 20, 2017).
Anions are chemical species that carry a negative electrical charge.
Anions are chemical species that carry a negative electrical charge. Comstock, Getty Images

An anion is an ion which has a negative charge. This is a table listing common anions and their formulas.

Table of Common Anions

Simple AnionsFormula
HydrideH-
OxideO2-
FluorideF-
SulfideS2-
ChlorideCl-
NitrideN3-
BromideBr-
IodideI-
  
OxoanionsFormula
ArsenateAsO43-
PhosphatePO43-
ArseniteAsO33-
Hydrogen PhosphateHPO42-
Dihydrogen PhosphateH2PO4-
SulfateSO42-
NitrateNO3-
Hydrogen SulfateHSO4-
NitriteNO2-
ThiosulfateS2O32-
SulfiteSO32-
PerchlorateClO4-
IodateIO3-
ChlorateClO3-
BromateBrO3-
ChloriteClO2-
HypochloriteOCl-
HypobromiteOBr-
CarbonateCO32-
ChromateCrO42-
Hydrogen Carbonate or BicarbonateHCO3-
DichromateCr2O72-
  
Anions from Organic AcidsFormula
AcetateCH3COO-
FormateHCOO-
  
Other AnionsFormula
CyanideCN-
AmideNH2-
CyanateOCN-
PeroxideO22-
ThiocyanateSCN-
OxalateC2O42-
HydroxideOH-
PermanganateMnO4-

Writing Formulas of Salts

Salts are compounds composed of cations bonded to anions. The resulting compound carries a neutral electrical charge. For example, table salt or sodium chloride consists of the Na+ cation bonded to the Cl- anion to form NaCl. Salts are hygroscopic or tend to pick up water. This water is called water of hydration. By convention, the cation name and formula is listed before the anion name and formula. In other words, write the cation on the left and the anion on the right.

The formula of a salt is:

(cation)m(anion)n·(#)H2O

Where the H2O is omitted if the # is zero, m is the oxidation state of the anion and n is the oxidation state of the anion. If m or n is 1, then no subscript is written in the formula.

The name of a salt is given by:

(cation)(anion) (prefix)(hydrate) where the hydrate is omitted if there is no water

Prefixes indicate the number of water molecules or can be used in front of the cation and anion names in cases where the cation (usually) can have multiple oxidation states.

Common prefixes are:

NumberPrefix
1mono
2di
3tri
4tetra
5penta
6hexa
7hepta
8octa
9nona
10deca
11undeca

For example, the compound strontium chloride consists of the cation Sr2+ combined with the anion Cl-. It is written SrCl2.

When the cation and/or the anion is a polyatomic ion, parentheses may be used to group the atoms in the ion together to write the formula.

For example, the salt ammonium sulfate consists of the cation NH4+ and the sulfate anion SO42-. The formula of the salt is written as (NH4)2SO4. The compound calcium phosphate consists of the calcium cation Ca2+ with the anion PO43- and is written as Ca3(PO4)2.

An example of a formula that includes water of hydrate is that of copper(II) sulfate pentahydrate. Note that the name of the salt includes the oxidation state of copper. This is common when dealing with any transition metal or rare earth. The formula is written as CuSO4·5H2O.

Formulas of Binary Inorganic Compounds

Combining cations and anions to form binary inorganic compounds is simple. The same prefixes are applied to indicate the quantities of cation or anion atoms. Examples include the name of water, H2O, which is dihydrogen monoxide, and the name of NO, which is nitrogen dioxide.

Cations and Anions in Organic Compounds

The rules for naming and writing the formulas of organic compounds are more complex. In general, the name follows the rule:

(group prefixes)(longest carbon chain prefix)(highest root bond)(most important group suffix)

Format
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Your Citation
Helmenstine, Anne Marie, Ph.D. "Common Anions Table and Formulas List." ThoughtCo, May. 5, 2017, thoughtco.com/common-anions-table-and-formulas-list-603961. Helmenstine, Anne Marie, Ph.D. (2017, May 5). Common Anions Table and Formulas List. Retrieved from https://www.thoughtco.com/common-anions-table-and-formulas-list-603961 Helmenstine, Anne Marie, Ph.D. "Common Anions Table and Formulas List." ThoughtCo. https://www.thoughtco.com/common-anions-table-and-formulas-list-603961 (accessed September 20, 2017).