Science, Tech, Math › Science Dative Bond Definition (Coordinate Bond) Share Flipboard Email Print Thomas Demarczyk / Getty Images Science Chemistry Chemical Laws Basics Molecules Periodic Table Projects & Experiments Scientific Method Biochemistry Physical Chemistry Medical Chemistry Chemistry In Everyday Life Famous Chemists Activities for Kids Abbreviations & Acronyms Biology Physics Geology Astronomy Weather & Climate By Anne Marie Helmenstine, Ph.D. Chemistry Expert Ph.D., Biomedical Sciences, University of Tennessee at Knoxville B.A., Physics and Mathematics, Hastings College Dr. Helmenstine holds a Ph.D. in biomedical sciences and is a science writer, educator, and consultant. She has taught science courses at the high school, college, and graduate levels. our editorial process Facebook Facebook Twitter Twitter Anne Marie Helmenstine, Ph.D. Updated October 14, 2019 A covalent bond forms when two atoms share electrons. The electron pair is attracted to both atomic nuclei, holding them together to form a bond. In a typical covalent bond, each atom supplies an electron to form the bond. A dative bond is a covalent bond between two atoms where one of the atoms provides both electrons that form the bond. A dative bond is also known as a dipolar bond or coordinate bond. In a diagram, a dative bond is indicated by drawing an arrow pointing from the atom that donates the lone electron pair toward the atom that accepts the pair. The arrow replaces the usual line that indicates a chemical bond. Key Takeaways: Dative Bond A dative bond is a 2-center, 2-electron covalent bond in which both electrons come from the same atom.A dative bond is also called a coordinate covalent bond or a coordinate bond.Dative bonds are common when metal ions bind to ligands. Dative Bond Example Dative bonds are commonly seen in reactions involving hydrogen (H) atoms. For example, when hydrogen chloride dissolves in water to make hydrochloric acid, a dative bond is found in the hydronium ion: H2O + HCl → H3O+ + Cl- The hydrogen nucleus is transferred to the water molecule to form hydronium, so it does not contribute any electrons to the bond. Once the bond is formed, there is no difference between a dative bond and an ordinary covalent bond. Source Greenwood, Norman N.; Earnshaw, Alan. "Chemistry of the Elements" (2nd ed.). Butterworth-Heinemann, 1997, Oxford.