Titrant Definition in Chemistry

Chemistry Glossary Definition of Titrant

A titrant is a solution of known concentration.
A titrant is a solution of known concentration. Corbis via Getty Images / Getty Images

Titrant Definition

In analytical chemistry, the titrant is a solution of known concentration which is added (titrated) to another solution to determine the concentration of a second chemical species. The titrant may also be called the titrator, the reagent, or the standard solution.

In contrast, the analyte or titrand is the species of interest during a titration. When a known concentration and volume of titrant is reacted with the analyte, it's possible to determine the analyte concentration.

How It Works

The mole ratio between the reactants and products in a chemical equation is the key to using titration to determine an unknown concentration of a solution. Typically, a flask or beaker containing a precisely known volume of analyte, together with an indicator, is placed under a calibrated burette or pipette. The burette or pipette contains the titrant, which is added dropwise until the indicator shows a color change, indicating the titration endpoint. Color change indicators are tricky, because color may temporarily change before permanently changing. This introduces some degree of error in the calculation. When the endpoint is reached, the volume of reactant is determined using the equation:

Ca = CtVtM/Va

Where Ca is the analyte concentration (usually given as molarity), Ct is titrant concentration (in the same units), Vt is the volume of titrant required to reach the endpoint (usually in liters), M is the mole ration between the analyte and reactant from the balanced equation, and Va is the analyte volume (usually in liters).