Science, Tech, Math › Science Ionic vs Covalent Bonds - Understand the Difference Share Flipboard Email Print Electrons in a covalent bond are shared equally, while electrons in an ionic bond spend more time closer to one atom than the other. PASIEKA / Getty Images Science Chemistry Basics Chemical Laws Molecules Periodic Table Projects & Experiments Scientific Method Biochemistry Physical Chemistry Medical Chemistry Chemistry In Everyday Life Famous Chemists Activities for Kids Abbreviations & Acronyms Biology Physics Geology Astronomy Weather & Climate By Anne Marie Helmenstine, Ph.D. Chemistry Expert Ph.D., Biomedical Sciences, University of Tennessee at Knoxville B.A., Physics and Mathematics, Hastings College Dr. Helmenstine holds a Ph.D. in biomedical sciences and is a science writer, educator, and consultant. She has taught science courses at the high school, college, and graduate levels. our editorial process Facebook Facebook Twitter Twitter Anne Marie Helmenstine, Ph.D. Updated January 23, 2020 A molecule or compound is made when two or more atoms form a chemical bond, linking them together. The two types of bonds are ionic bonds and covalent bonds. The distinction between them has to do with how equally the atoms participating in the bond share their electrons. Ionic Bonds In an ionic bond, one atom essentially donates an electron to stabilize the other atom. In other words, the electron spends most of its time close to the bonded atom. Atoms that participate in an ionic bond have different electronegativity values from each other. A polar bond is formed by the attraction between oppositely-charged ions. For example, sodium and chloride form an ionic bond, to make NaCl, or table salt. You can predict an ionic bond will form when two atoms have different electronegativity values and detect an ionic compound by its properties, including a tendency to dissociate into ions in water. Covalent Bonds In a covalent bond, the atoms are bound by shared electrons. In a true covalent bond, the electronegativity values are the same (e.g., H2, O3), although in practice the electronegativity values just need to be close. If the electron is shared equally between the atoms forming a covalent bond, then the bond is said to be nonpolar. Usually, an electron is more attracted to one atom than to another, forming a polar covalent bond. For example, the atoms in water, H2O, are held together by polar covalent bonds. You can predict a covalent bond will form between two nonmetallic atoms. Also, covalent compounds may dissolve in water, but don't dissociate into ions. Ionic vs Covalent Bonds Summary Here's a quick summary of the differences between ionic and covalent bonds, their properties, and how to recognize them: Ionic Bonds Covalent Bonds Description Bond between metal and nonmetal. The nonmetal attracts the electron, so it's like the metal donates its electron to it. Bond between two nonmetals with similar electronegativities. Atoms share electrons in their outer orbitals. Polarity High Low Shape No definite shape Definite shape Melting Point High Low Boiling Point High Low State at Room Temperature Solid Liquid or Gas Examples Sodium chloride (NaCl), Sulfuric Acid (H 2SO 4 ) Methane (CH 4), Hydrochloric acid (HCl) Chemical Species Metal and nometal (remember hydrogen can act either way) Two nonmetals Do you understand? Test your comprehension with this quiz. Key Points The two main types of chemical bonds are ionic and covalent bonds. An ionic bond essentially donates an electron to the other atom participating in the bond, while electrons in a covalent bond are shared equally between the atoms. The only pure covalent bonds occur between identical atoms. Usually, there is some polarity (polar covalent bond) in which the electrons are shared, but spend more time with one atom than the other. Ionic bonds form between a metal and a nonmetal. Covalent bonds form between two nonmetals. Cite this Article Format mla apa chicago Your Citation Helmenstine, Anne Marie, Ph.D. "Ionic vs Covalent Bonds - Understand the Difference." ThoughtCo, Feb. 16, 2021, thoughtco.com/ionic-and-covalent-chemical-bond-differences-606097. Helmenstine, Anne Marie, Ph.D. (2021, February 16). Ionic vs Covalent Bonds - Understand the Difference. Retrieved from https://www.thoughtco.com/ionic-and-covalent-chemical-bond-differences-606097 Helmenstine, Anne Marie, Ph.D. "Ionic vs Covalent Bonds - Understand the Difference." ThoughtCo. https://www.thoughtco.com/ionic-and-covalent-chemical-bond-differences-606097 (accessed July 25, 2021). copy citation Watch Now: How To Make A Chemical Bond Polar Bond Definition and Examples Bonds Definition in Chemistry The Main Types of Chemical Bonds Compounds With Both Ionic and Covalent Bonds Ionic Compound Properties, Explained Examples of Polar and Nonpolar Molecules Why Do Atoms Create Chemical Bonds? What Is a Covalent Bond in Chemistry? What Is Electronegativity and How Does It Work? What Type of Bonds Does Carbon Form? Examples of Ionic Bonds and Compounds Weak Acid Definition and Examples in Chemistry Nonpolar Molecule Definition and Examples Why Is Water a Polar Molecule? Why the Formation of Ionic Compounds Is Exothermic What Are Some Examples of Covalent Compounds?