Solubility Rules of Ionic Solids

Solubility Rules of Ionic Solids in Water

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This is a list of the solubility rules for ionic solids in water. Solubility is a result of an interaction between polar water molecules and the ions which make up a crystal. Two forces determine the extent to which solution will occur:

Force of Attraction Between H2O Molecules and the Ions of the Solid

This force tends to bring ions into solution. If this is the predominant factor, then the compound may be highly soluble in water.

Force of Attraction Between Oppositely Charged Ions

This force tends to keep the ions in the solid state. When it is a major factor, then water solubility may be very low.

However, it is not easy to estimate the relative magnitudes of these two forces or to quantitatively predict water solubilities of electrolytes. Therefore, it is easier to refer to a set of generalizations, sometimes called "solubility rules," that are based upon experimentation. It's a good idea to memorize the information in this table.

Solubility Rules

All salts of the group I elements (alkali metals = Na, Li, K, Cs, Rb) are soluble.

NO3: All nitrates are soluble.

Chlorate (ClO3-), perchlorate (ClO4-), and acetate (CH3COO- or C2H3O2-, abbreviated as Oac-) salts are soluble.

Cl, Br, I: All chlorides, bromides, and iodides are soluble except those of silver, mercury, and lead (e.g., AgCl, Hg2Cl2, and PbCl2).

SO42: Most sulfates are soluble.

Exceptions include BaSO4, PbSO4, and SrSO4.

CO32: All carbonates are insoluble except NH4+ and those of the Group 1 elements.

OH: All hydroxides are insoluble except those of the Group 1 elements, Ba(OH)2, and Sr(OH)2. Ca(OH)2 is slightly soluble.

S2: All sulfides are insoluble except those of the Group 1 and Group 2 elements and NH4+.

More About Solubility

Using Solubility To Predict Precipitates
Solubility Product Constants

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Helmenstine, Anne Marie, Ph.D. "Solubility Rules of Ionic Solids." ThoughtCo, Feb. 5, 2018, Helmenstine, Anne Marie, Ph.D. (2018, February 5). Solubility Rules of Ionic Solids. Retrieved from Helmenstine, Anne Marie, Ph.D. "Solubility Rules of Ionic Solids." ThoughtCo. (accessed February 25, 2018).