What Are Standard State Conditions? - Standard Temperature and Pressure

Know the Standard State Conditions

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Values of thermodynamic quantities are commonly expressed for standard state conditions, so it is a good idea to understand what the standard state conditions are.

A superscript circle is used to denote a thermodynamic quantity that is under standard state conditions:

ΔH = ΔH°
ΔS = ΔS°
ΔG = ΔG°

Standard State Conditions

Certain assumptions apply to standard state conditions. Standard temperature and pressure commonly is abbreviated as STP.

  • The standard state temperature is 25°C (298 K). It is possible to calculate standard state values for other temperatures.
  • All liquids are pure.
  • The concentration of all solutions is 1 M (1 molar).
  • All gases are pure.
  • All gases are at 1 atm pressure.
  • The energy of formation of an element in its normal state is defined as zero.
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Helmenstine, Anne Marie, Ph.D. "What Are Standard State Conditions? - Standard Temperature and Pressure." ThoughtCo, Mar. 15, 2017, thoughtco.com/standard-state-conditions-overview-609256. Helmenstine, Anne Marie, Ph.D. (2017, March 15). What Are Standard State Conditions? - Standard Temperature and Pressure. Retrieved from https://www.thoughtco.com/standard-state-conditions-overview-609256 Helmenstine, Anne Marie, Ph.D. "What Are Standard State Conditions? - Standard Temperature and Pressure." ThoughtCo. https://www.thoughtco.com/standard-state-conditions-overview-609256 (accessed May 26, 2018).