What Is Litmus Paper?

Litmus Paper and the Litmus Test

Litmus paper is used to test pH. Blue litmus paper turns red under acidic conditions, while red litmus paper turns blue under alkaline conditions.
Litmus paper is used to test pH. Blue litmus paper turns red under acidic conditions, while red litmus paper turns blue under alkaline conditions. David Gould / Getty Images

You can make paper test strips to determine the pH of an aqueous solution by treating filter paper with any of the common pH indicators. One of the first indicators used for this purpose was litmus. Litmus paper is paper that has been treated with a specific indicator - a mixture of 10-15 natural dyes obtained from lichens (mainly Roccella tinctoria) that turns red in response to acidic conditions (pH 7).

When the pH is neutral (pH = 7) then the dye is purple. The first known use of litmus was around 1300 AD by Spanish alchemist Arnaldus de Villa Nova. The blue dye has been extracted from lichens since the 16th century. The word "litmus" comes from the old Norse word for "to dye or color".

Litmus Test

To perform the test, simple place a drop of liquid sample on a small strip of paper or dip a piece of litmus paper in a small specimen of the sample. Ideally, you don't dip litmus paper in an entire container of a chemical.

The litmus test is a quick method of determining whether a liquid or gaseous solution is acidic or basic (alkaline). The test can be performed using litmus paper or an aqueous solution containing litmus dye. Initially, litmus paper is either red or blue. The blue paper changes color to red, indicating acidity somewhere between the pH range of 4.5 to 8.3 (however, note 8.3 is alkaline).

 Red litmus paper can indicate alkalinity with a color change to blue. In general, litmus paper is red below pH of 4.5 and blue above a pH of 8.3.

If the paper turns purple, this indicates the pH is near neutral. Red paper that does not change color indicates the sample is an acid. Blue paper that does not change color indicates the sample is a base.

Remember, acids and bases only refer to aqueous (water-based) solutions, so pH paper won't change color in non-aqueous liquids, such as vegetable oil.

Litmus paper may be dampened with distilled water to give a color change for a gaseous sample. Gases change the color of the entire litmus strip, since the whole surface is exposed. Neutral gases, such as oxygen and nitrogen, do not change the color of the pH paper.

Litmus paper that has changed from red to blue can be reused as blue litmus paper. Paper that has changed from blue to red can be reused as red litmus paper.

Limitations of the Litmus Test

The litmus test is quick and simple, but it suffers a few limitations. First, it's not an accurate indicator of pH. It does not yield a numerical pH value. Instead, it roughly indicates whether a sample is an acid or a base. Second, the paper can change colors for other reasons besides an acid-base reaction. For example, blue litmus paper turns white in chlorine gas. This color change is due to bleaching of the dye from hypochlorite ions, not acidity/basicity.

Alternatives to Litmus Paper

Litmus paper is handy as a general acid-base indicator, but you can get much more specific results if you use an indicator that has a more narrow test range or that offers a wider color range.

Red cabbage juice, for example, changes color in response to pH all the way from red (pH = 2) through blue at neutral pH to greenish-yellow at pH = 12, plus you are more likely to find cabbage at the local grocery store than lichen.

Thedyes orcein  and azolitmin yield results comparable to those of litmus paper.